Pd-Catalyzed C(sp 3)-H Biarylation through Transient Directing Group Technique

cromauv.org

Pd-Catalyzed C(sp 3)-H Biarylation through Transient Directing Group Technique

Right here, we describe a extremely selective Pd-catalyzed C(sp3)-H biarylation of 2-methylbenzaldehydes utilizing cyclic diaryliodonium salts as arylation reagents. The important thing technique is the employment of tert-leucine as a bidentate transient directing group for the proximity-driven metalation to realize reactivity and selectivity in C-H activation. Numerous functionalized biaryls bearing each aldehyde and iodine practical teams have been ready efficiently, which may very well be additional remodeled into a variety of compounds with potential functions in pharmaceutical chemistry and supplies science.

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Non-Sterile Microcentrifuge Tube 1.5mL (Eppendorf Safe-Lock)

TUBE1EP5 500box
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Description: Eppendorf® Safe-Lock™ 1.5 mL snap-cap tubes for microcentrifuge style Bullet Blenders. Non-sterile.

Non-Sterile Microcentrifuge Tube 2.0mL (Eppendorf Safe-Lock)

TUBE2EP 500box
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Description: Eppendorf® Safe-Lock™ 2 mL snap-cap tubes for regular and Blue model snap cap Bullet Blenders. Non-sterile.

Safe-Green™ 2X PCR Bestaq™ MasterMix

G478 5.0 ml (200 Rxns)
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1000UL AXYGEN MULTIRACK EXTENDED PIPET TIP RACKED 768/PACK 5 PACK/CASE

MR-1000XT-R 768/pk
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Description: Non Filter Tips; Multi Rack Tips

1000UL AXYGEN MULTIRACK EXTENDED PIPET TIP RELOAD 768/PACK 4 PACK/CASE

MR-1000XT-RL 768/pk
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StarLight Collection - Slide 4-Pack

SL04K 1 pack
EUR 420.41
Description: StarLight Collection - Slide 4-Pack are  fluorescent microspheres dyed with a single fluorophore for basic imaging checks and calibration for fluorescence microscopes. 

0.6ML MICROTUBES IN SPECTRUM PACK

MCT-060-SP 1000/pk
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MCT-175-SP 500/pk
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3 Blocking Buffer Sample Pack

KF17340 3 x 100 ml
EUR 205

All Assay Diluents Sample Pack

KF17351 4X100 ml
EUR 272

All Sample Diluents Sample Pack

KF17355 3X100 ml
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CP-C100-5 5pack
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Description: Pipette Checkit Pro model for 100uL pipettes. Pack of 5.

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CP-C20-5 5pack
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Description: Pipette Checkit Pro model for 20uL pipettes. Pack of 5.

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CP-C200-5 5pack
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Checkit Pro C50 - 5 pack

CP-C50-5 5pack
EUR 179
Description: Pipette Checkit Pro model for 50uL pipettes. Pack of 5.

Bead Sample Pack - 50mL Set

BSP-50B2 1pack
EUR 404
Description: Bead sample pack for Bullet Blender 50mL tube models. Includes 20mL of: ZROB05, ZROB20, SSB02, SSB14B, SSB48, SSB60, SSUFO35 and SSUFO56.

Bead Sample Pack - 5E Set

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Description: Bead sample pack for Bullet Blender 5E models. Includes 10mL of: ZROB015, ZROB05, ZROB20, SSB02, SSB14B, SSB32, SSB48, SSUFO35 and SSUFO56.

Bead Sample Pack - 5M Set

BSP-5Y 1pack
EUR 241
Description: Bead sample pack for Bullet Blender 5mL Storm models. Includes 10mL of: ZROB015, ZROB05, ZROB20, SSB02, SSB14B, SSB32, SSB60, SSB110 and SSUFO35.

Bead Sample Pack - Full Set

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Description: Bead sample pack inlcudes sampling of all 20 bead types in 10mL tubes.

Bead Sample Pack - Cell Cultures

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Description: Bead sample pack for homogenization of cell cultures. Includes 10mL of: GB01, GB05, ZROB015, ZROB05 and SSB02.

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BSP-MC2 1pack
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Description: Bead sample pack for Bullet Blender 1.5mL tube models. Includes 10mL of: ZROB015, ZROB05, ZROB10, ZROB20, SSB02, SSB14B, SSB32 and SSUFO35.

Bead Sample Pack - Organ Tissues

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Description: Bead sample pack for homogenization of organ tissues. Includes 10mL of: ZROB05, ZROB10, ZROB20, SSB14B, SSB32 and SSUFO35.

200ul Natural Tip, 1000/Pack

BT228 1PK, 1000UNIT
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BT999 1PK, 250UNIT
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CORNING LAMBDA ELITETOUCH STARTER PACK

6065 1/pk
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Description: Corning and Axygen Liquid Handling Equipment; Corning Lambda Plus Single Channel Pipettors

50X TAE Buffer, Refill Pack

T8050-204 3.5L Ask for price

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T8057-401 1 Gal
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ACK500 530 ml
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TMB Peroxidase Substrate SAMPLE PACK

42R-TB101 3 x 100 ml
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Description: 100mL of 3 different TMB Peroxidase Substrates ready to use in immunoassays: Ultra sensitivite, Highly Sensitive, and Slow Acting.

Red Blood Cell Sample Pack

88R-1050 6 x 2 ml
EUR 403
Description: Horse, Mouse, Rabbit, Sheep, Bovine and Chicken glutaraldehyde stabilized blood cell samples

10UL AXYGEN MULTIRACK EXTENDED LENGTH PIPET TIP RACKED, 960/PACK 5 PACK/CASE

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Genome editeid iPSCs (KI) Safe harbor CAG-GFP-chr19-hetero

ASE-9503 1 vial (1 x 10^6)
EUR 3087.5
Description: 12 month

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ASE-9504 1 vial (1 x 10^6)
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AAVS1 Safe Harbor cDNA/miRNA Donor Vector [pAAVS1D-PGK.MCS-EF1a.copGFPpuro]

GE602A-1 10 ug
EUR 1268

AAVS1 Safe Harbor Positive Control Donor Vector [pAAVS1D-CMV.RFP-EF1a.copGFPpuro]

GE603A-1 10 ug
EUR 1268

1000UL AXYGEN MULTIRACK EXTENDED PIPET TIP RACKED,STERILE 768/PACK 5 PACK/CASE STERILE

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Histone H3K4 Methylation Antibody Panel Pack

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EUR 628.55
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Histone H3K9 Methylation Antibody Panel Pack

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EUR 628.55
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Histone H3K27 Methylation Antibody Panel Pack

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EUR 628.55
Description: The best epigenetics products

Histone H3K36 Methylation Antibody Panel Pack

C10008 3 x 25 µg
EUR 628.55
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Histone H3K79 Methylation Antibody Panel Pack

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Histone H4K20 Methylation Antibody Panel Pack

C10012 3 x 25 µg
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Histone H4 Acetylation Antibody Panel Pack

C10013 4 x 25 µg
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Histone H3 Phosphorylation Antibody Panel Pack

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Histone H3R2 Methylation Antibody Panel Pack

C10015 3 x 25 µg
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Histone H3R17 Methylation Antibody Panel Pack

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Histone H3R26 Methylation Antibody Panel Pack

C10018 3 x 25 µg
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Histone H4R3 Methylation Antibody Panel Pack

C10019 3 x 25 µg
EUR 628.55
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DNA Methylation Antibody Panel Pack I

C20000
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SensiTek HRP Anti-Mouse Lab Pack

SHM999 10000 Slides
EUR 1311

assisted disposable sensors for quantitative willpower of

A way for willpower of arsenic is described. The sensor was constructed by immobilizing reagents on TLC (skinny layer chromatography) paper. The response is predicated on chromogenic response of arsenic with a coupling advanced of sulfanilic acid and N-(1-naphthyl) ethylene diamine dihydrochloride (NEDA) and formation of purple to magenta spots adopted by scanner primarily based detection. Modifications in RGB values of colour spots on TLC strips create a sample.

The obtained sample was analyzed utilizing MATLAB software program. The proposed sensor is linear within the vary 1-10 and 25-100 μg mL -1. The minimal detection restrict discovered was 0.018 μg mL-1of arsenic.

One-step conversion of to its utilizing salts for GC-MSdetection of bacterial endospores

Methyl sulfate (MeSO4-) salts have been explored as thermochemolysis-methylation (TCM) reagents for fuel chromatographic (GC) evaluation of dipicolinic acid (DPA) as its dimethyl ester (Me2DPA) from bacterial endospores. The response was carried out below non-pyrolytic situations by inserting a small coiled wire filament coated with the pattern and reagents straight inside a GC injection port at 290 °C. Above 10 : 1 methyl donor/DPA ratios, alkali steel salts of MeSO4- effected 80-90% conversion of DPA to Me2DPA, which was 10-20 occasions extra energetic than the identical quantity of tetramethylammonium hydroxide (TMA-OH) at this temperature.

A quaternary salt combination consisting of 1 : 3 : 1 : Three TMA+/Na+/OH-/MeSO4- methylated spore DPA with a median conversion of 86% (imply conversion by TMA-OH below the identical situations was 4%). Due to this fact, the sensitivity for detection of bacterial endospores was elevated over 20-fold in comparison with that noticed with the extra generally employed TMA-OH methylating reagent. The restrict of detection by this technique was 9 × 104 whole spores. Mechanisms describing the noticed conduct are proposed and mentioned. That is the primary use of MeSO4- as a TCM reagent for GC.

Progress in direction of the characterisation of faecal compounds

Intestinal nitrosation produces ATNCs (Obvious Whole N-nitroso Compounds) and these have been linked with an elevated threat of colon most cancers from consuming pink meat. Fashionable LC-MS instrumentation makes direct detection of ATNC elements in faecal water a chance.

The issue is in figuring out which of the numerous compounds current are N-nitrosamines earlier than embarking on efforts to characterise them. We now have assumed that any in vivo nitrosation of alimentary tract contents shall be non-specific and depend upon the quantity and basicity of amine current, with focus of nitrosating agent being the limiting issue.

By additional nitrosating faecal waters (and ileostomy fluids) we will improve the quantity of ATNC and readily entry these compounds. The quantity and the variety of nitrosamines generated depend upon the focus of particular person amines current. By derivatisation individually utilizing each 14N and 15N labelled nitrite, we demonstrated that inspecting chromatograms in parallel for a unit mass distinction supplies a novel and practicable means for figuring out unknown ATNC in faecal and ileostomy samples.

MS procedures have been linked with the normal approaches of thermal power analyser (TEA), preparative HPLC, visualisation of nitrosamines with Griess reagent and degradation of N-nitroso compounds by UV irradiation. We now have demonstrated that this method is repeatable and have used it to determine 30 putative N-nitroso compounds (as protonated mum or dad plenty [M + H]+ at: 242, 258, 312, 313, 333, 348, 365, 377, 382, 386, 392, 412, 414, 421, 434, 442, 466, 467, 483, 493, 572, 582, 625, 636, 637, 656, 662, 752, 808, and 870.  

4L ProtoBlue Safe

NAT1110 4L
EUR 235

Safe-Pack™

G108-P G108-WGR
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G108-R 1.0 ml
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Safe Image? Basic DNA Stain

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M1195-1000
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M1196-1000
EUR 234

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Safe Image Super? DNA Stain

M1198-1000
EUR 234

Bromocresol Green

GT4023-25G 25 g
EUR 110

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GT4023-5G 5 g
EUR 54

Leucomalachite Green

GT7606-10G 10 g
EUR 94

Leucomalachite Green

GT7606-25G 25 g
EUR 158

Leucomalachite Green

GT7606-5G 5 g
EUR 66

MitoView Green

70054 20X50UG
EUR 226
Description: Minimum order quantity: 1 unit of 20X50UG

Bromocresol green

20-abx186394
  • EUR 411.00
  • EUR 244.00
  • 100 g
  • 25 g

Brilliant green

BB0242 25g
EUR 56.09

Leucomalachite green

AG105 1 mg
EUR 523

Malachite green

AT060 1mg
EUR 1790

Leucomalachite green

AT105 1mg
EUR 1368

Malachite green

AG060 1 mg
EUR 523

Safe Image? Fire Red DNA Stain

M1199-1000
EUR 234

PhosLite™ Green

11630 1 mg
EUR 219

Thiolite™ Green

21508 5 mg
EUR 306

CytoTell™ Green

22253 500 Tests
EUR 132

CytoTell™ Green

22254 1000 Tests
EUR 176

LysoBrite™ Green

22643 500 Tests
EUR 176

ViSafe Green Gel

S435 500 µl
EUR 146

ViSafe Green Gel

S435L 5x500 µl
EUR 557

Green-DNA Dye

SB2040 100UL, 100UL
EUR 67.4

0.6ML MICROTUBES. GREEN

MCT-060-G 1000/pk
EUR 183
Description: Micro Tubes; Micro Tubes Push Cap- Axygen

1.7ML MICROTUBES. GREEN

MCT-175-G 500/pk
EUR 116
Description: Micro Tubes; Micro Tubes Push Cap- Axygen

Malachite green oxalate

MD0330 50g
EUR 57.83

Fast Green FCF

FB0452 5g
EUR 55.22

Fast Green FCF

HY-D0914 500mg
EUR 108

Malachite Green [HRP]

DAGA-073H 1mg
EUR 1170

Leucomalachite Green [HRP]

DAGA-074H 1mg
EUR 1105

Malachite Green [BSA]

DAGA-085B 1mg
EUR 780

Leucomalachite Green [BSA]

DAGA-086B 1mg
EUR 780

Malachite Green [KLH]

DAGA-091K 1mg
EUR 1105

Leucomalachite Green [KLH]

DAGA-092K 1mg
EUR 975

Indocyanine green(Cardiogreen)

E1KS1924 50 mg
EUR 247

Green Fluorescent Protein

MO22184 100 ul
EUR 409

5G Bromocresol Green

NAT1356 5G
EUR 156

10G Methyl Green

NAT1364 10G
EUR 176

Acid Green 50

GT1171-100G 100 g
EUR 86

Acid Green 50

GT1171-25G 25 g
EUR 46

Acid Green 50

GT1171-500G 500 g
EUR 229

Reactive Green 5

GT6783-25G 25 g
EUR 126

Reactive Green 5

GT6783-5G 5 g
EUR 54

Green Fluorescent Protein

CH22124 100 ul of 1 mg/ml
EUR 435

ViaVac Red/Green

29068 100uL
EUR 261
Description: Minimum order quantity: 1 unit of 100uL

BactoViewâ„¢ Live Green

40102 100uL
EUR 320
Description: Minimum order quantity: 1 unit of 100uL

Leuco- Malachiet green

AG131 1 mg
EUR 523

Green qPCR SuperMix

20-abx098031
  • EUR 1038.00
  • EUR 439.00
  • EUR 634.00
  • 15 ml
  • 1 ml
  • 5 ml

Fast Green FCF

abx082188-5g 5 g
EUR 203

Malachite green oxalate

abx180007-25g 25 g
EUR 272

C.I.Solvent Green 3

abx185369-25g 25 g
EUR 509

Fast Green Solution

FGN125 125 ml
EUR 66

Fast Green Solution

FGN500 500 ml
EUR 96

Fast Green Solution

FGN999 1000 ml
EUR 124

Malachite green Antibody

48363-100ul 100ul
EUR 333

Malachite green Antibody

48363-50ul 50ul
EUR 239

Green Algae Lysate

PABL-1306 50 ug
EUR 164

Light Green Solution

LGA030 30 ml
EUR 59

Light Green Solution

LGA125 125 ml
EUR 66

Light Green Solution

LGA3800 1 Gal.
EUR 271

Light Green Solution

LGA500 500 ml
EUR 101

Light Green Solution

LGA999 1000 ml
EUR 140

DNASE & METHYL GREEN

D04-102-10kg 10 kg
EUR 9392

DNASE & METHYL GREEN

D04-102-2kg 2kg
EUR 2081

DNASE & METHYL GREEN

D04-102-500g 500 g
EUR 602

BRILLIANT GREEN AGAR

B02-115-10kg 10 kg
EUR 1222

BRILLIANT GREEN AGAR

B02-115-2Kg 2 Kg
EUR 305

BRILLIANT GREEN AGAR

B02-115-500g 500 g
EUR 119

Malachite Green antibody

20-1184 100 ul
EUR 879
Description: Sheep polyclonal Malachite Green antibody

Accuris qMax Green

PR2000-H-100 1 PC
EUR 115.24

Accuris qMax Green

PR2000-H-1000 1 PC
EUR 467.74

Accuris qMax Green

PR2000-H-500 1 PC
EUR 284.31

Accuris qMax Green

PR2000-H-S 1 PC
EUR 73.77

Accuris qMax Green

PR2000-L-100 1 PC
EUR 115.24

Accuris qMax Green

PR2000-L-1000 1 PC
EUR 467.74

Accuris qMax Green

PR2000-L-500 1 PC
EUR 284.31

Accuris qMax Green

PR2000-L-S 1 PC
EUR 73.77

Accuris qMax Green

PR2000-N-100 1 PC
EUR 113.65

Accuris qMax Green

PR2000-N-1000 1 PC
EUR 459.76

Accuris qMax Green

PR2000-N-500 1 PC
EUR 279.53

Accuris qMax Green

PR2000-N-S 1 PC
EUR 72.98

Leucomalachite green-HRP

80-1192 500 ul
EUR 137
Description: Leucomalachite green Conjugate for use in immunoassays

SYBR Green I

B1747-25
EUR 1164

SYBR Green I

B1747-5
EUR 387

ER-Hunt Green

9548-100
EUR 446

Green Taq Mix

P131-01 5 ml
EUR 119

Green Taq Mix

P131-02 15 ml
EUR 150

Green Taq Mix

P131-03 50 ml
EUR 248

Sterile Microcentrifuge Tube 1.5mL (Eppendorf Safe-Lock)

TUBE1EP5-S 500box
EUR 161
Description: Eppendorf® Safe-Lock™ 1.5 mL snap-cap tubes for microcentrifuge style Bullet Blenders. Sterile, RNase & DNase free.

Sterile Microcentrifuge Tube 2.0mL (Eppendorf Safe-Lock)

TUBE2EP-S 500box
EUR 163
Description: Eppendorf® Safe-Lock™ 2 mL snap-cap tubes for regular and Blue model snap cap Bullet Blenders. Sterile, RNase & DNase free.

MMP Green™ substrate

13520 1 mg
EUR 480

Nuclear Green™ LCS1

17540 0.5 ml
EUR 132

Nuclear Green™ DCS1

17550 0.5 ml
EUR 132

Protonex™ Green 500

21215 1 mg
EUR 219

MitoLite™ Green EX488

22675 500 Tests
EUR 132

MitoLite™ Green FM

22695 10x50 ug
EUR 176

MycoLight™ Green JJ98

24000 100 ul
EUR 219

MycoLight™ Green JJ99

24001 100 ul
EUR 219

Light green SF, Yellowish

LD0007 25g
EUR 75.23

Novel Green PLUS (20000X)

LD003-0500 500 µl
EUR 172

Novel Green PLUS (20000X)

LD003-0500L 5x500 µl
EUR 731

Green Lysis Kit 50

GREENE1 50pack
EUR 156
Description: Bead lysis kits for the homogenization of small, tough samples. Pack of 50, 1.5mL Eppendorf Safe-Lock tubes prefilled with beads.

Green Lysis Kit 250

GREENE5 250pack
EUR 468
Description: Bead lysis kits for the homogenization of small, tough samples. Pack of 250, 1.5mL Eppendorf Safe-Lock tubes prefilled with beads.

80-Well Rack, Green

R567-G 1 UNIT
EUR 52.51

Malachite Green ELISA Kit

DEIA057 96T
EUR 1251
Description: The Malachite Green ELISA Kit is a direct competitive enzyme immunoassay for the quantitative analysis of Malachite green in fish and shrimp samples.

Bromocresol green, sodium salt

ED0087 5g
EUR 63.92

Green Fluorescent Protein (GFP)

MO22190 100 ul
EUR 409

25G Fast Green FCF

NAT1348 25G
EUR 160

Green Fluorescent Protein (GFP)

RA22134 100 ul of 1 mg/ml
EUR 409

Polycaspase Assay Kit, green

KF17200 25 Tests
EUR 304

Bromocresol Green sodium salt

GT3714-100G 100 g
EUR 229

Bromocresol Green sodium salt

GT3714-25G 25 g
EUR 110

Bromocresol Green sodium salt

GT3714-5G 5 g
EUR 54

Brilliant Green (C.I. 42040)

GT6123-100G 100 g
EUR 78

Brilliant Green (C.I. 42040)

GT6123-25G 25 g
EUR 46

Malachite green carbinol base

GT7477-100G 100 g
EUR 96

Methyl Green (C.I. 42585)

GT7495-100G 100 g
EUR 198

Methyl Green (C.I. 42585)

GT7495-25G 25 g
EUR 94

Methyl Green (C.I. 42585)

GT7495-5G 5 g
EUR 54

Malachite Green carbinol hydrochloride

GT8088-100G 100 g
EUR 114

Malachite Green carbinol hydrochloride

GT8088-25G 25 g
EUR 54

Green Fluorescent Protein (GFP)

CH23105 400 ul
EUR 761

MitoView Green, Trial Size

70054-T 50UG
EUR 94
Description: Minimum order quantity: 1 unit of 50UG

Bromocresol green, free acid

BD0159 5g
EUR 63.92

Green qPCR SuperMix UDG

20-abx098032
  • EUR 1135.00
  • EUR 453.00
  • EUR 662.00
  • 15 ml
  • 1 ml
  • 5 ml

Top Green qPCR SuperMix

20-abx098033
  • EUR 829.00
  • EUR 217.00
  • EUR 1135.00
  • EUR 411.00
  • 15 ml
  • 1 ml
  • 25 ml
  • 5 ml

Tip Green qPCR SuperMix

20-abx098034
  • EUR 968.00
  • EUR 230.00
  • EUR 1330.00
  • EUR 467.00
  • 15 ml
  • 1 ml
  • 25 ml
  • 5 ml

Recombinant Green Fluorescent Protein

7-06112 10µg Ask for price

Recombinant Green Fluorescent Protein

7-06113 50µg Ask for price

Recombinant Green Fluorescent Protein

7-06114 1mg Ask for price

Trichrome Stain Solution (Green)

TGG125 125 ml
EUR 88

Trichrome Stain Solution (Green)

TGG500 500 ml
EUR 116

Trichrome Stain Solution (Green)

TGG999 1000 ml
EUR 143

Light Green Solution (0.1%)

LGD-10000 10 L
EUR 886

Light Green Solution (0.1%)

LGD125 125 ml
EUR 72

Light Green Solution (0.1%)

LGD3800 1 Gal.
EUR 397

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